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States of Matter & Gas Laws

Liquefaction of Gases

The conversion of a gas into a liquid by cooling below its critical temperature and applying pressure.

Unit K

In depth

Cooling must come first, since compression alone cannot liquefy a gas above its critical temperature. Industrially, gases are liquefied by repeated compression and Joule–Thomson expansion in a regenerative Linde cycle, or by expansion against a piston that extracts work.

Examples in the real world

Liquid nitrogen at −196 °C for cryogenic storage; LPG cylinders holding propane liquefied under modest pressure.