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Chemical Kinetics & Catalysis

Average Rate

The overall change in concentration divided by the total time interval over which it occurred.

Formula / equation rate_avg = Δ[A] / Δt
Unit mol/(L·s)

In depth

Average rate is easy to measure but conceals how the rate varies during the interval. Because most reactions decelerate as reactants are used up, the average over a long period is much smaller than the initial rate and is of limited use in determining a rate law.

Examples in the real world

A reaction consuming 0.20 mol/L over 100 s has an average rate of 2.0 × 10⁻³ mol/(L·s).