Results for “Covalent Bond”
20 terms
Covalent Bond
Chemical Bonding & Molecular Structure
kJ/mol
A bond formed when two atoms share one or more pairs of electrons so that both achieve a stable configuration.
A· + ·B → A:B
Polar Covalent Bond
Chemical Bonding & Molecular Structure
D
A covalent bond in which the shared electrons are unequally distributed because the bonded atoms differ in electronegativity.
δ⁺A—Bδ⁻
Bond Polarity
Chemical Bonding & Molecular Structure
Dimensionless
The degree of unequal electron sharing in a covalent bond, arising from an electronegativity difference between the bonded atoms.
Δχ = |χ_A − χ_B|
Coordinate Bond
Chemical Bonding & Molecular Structure
kJ/mol
A covalent bond in which both shared electrons are supplied by the same atom.
A: + B → A→B
Cross-Linking
Biochemistry & Polymer Chemistry
Dimensionless
The formation of covalent bonds between separate polymer chains.
Electronegativity
Atomic Structure & Periodicity
Dimensionless
The relative tendency of an atom in a covalent bond to attract the shared pair of electrons towards itself.
ΔEN determines bond polarity
Molecule
Foundations of Chemistry
Dimensionless
An electrically neutral group of two or more atoms held together by covalent bonds, acting as the smallest unit of a covalent substance.
Nucleophile
Organic Chemistry
Dimensionless
An electron-rich species that donates a pair of electrons to form a new covalent bond.
Nu⁻ or Nu:
Pi Bond
Chemical Bonding & Molecular Structure
kJ/mol
A covalent bond formed by the sideways overlap of parallel p orbitals, with electron density above and below the internuclear axis.
Polymer
Biochemistry & Polymer Chemistry
g/mol
A large molecule built from many repeating structural units joined by covalent bonds.
–(A)ₙ–
Sigma Bond
Chemical Bonding & Molecular Structure
kJ/mol
A covalent bond formed by the head-on overlap of atomic orbitals, with electron density concentrated along the internuclear axis.
Valence Bond Theory
Chemical Bonding & Molecular Structure
Dimensionless
The bonding model in which a covalent bond forms by the overlap of half-filled atomic orbitals on adjacent atoms.
Atomic Orbital
Atomic Structure & Periodicity
Dimensionless
A mathematical function describing the region around a nucleus where an electron of given energy is most likely to be found.
|ψ|² = probability density
Atomicity
Foundations of Chemistry
Dimensionless
The number of atoms present in one molecule of an element.
Chalcogens
Atomic Structure & Periodicity
Dimensionless
The group 16 elements — oxygen, sulfur, selenium, tellurium and polonium — collectively known as the ore-forming elements.
ns² np⁴
Intermolecular Forces
Chemical Bonding & Molecular Structure
kJ/mol
The comparatively weak attractions acting between separate molecules rather than within them.
Organic Chemistry
Organic Chemistry
Dimensionless
The study of the structure, properties, composition and reactions of carbon-containing compounds.
Thermoplastic
Biochemistry & Polymer Chemistry
°C
A polymer that softens on heating and hardens again on cooling, reversibly and repeatedly.
Water of Crystallisation
Foundations of Chemistry
mol per mol
Water molecules chemically bound within the crystal lattice of a hydrated salt in a fixed stoichiometric ratio.
Chemical Bond
Chemical Bonding & Molecular Structure
kJ/mol
The attractive force that holds atoms or ions together in a stable chemical species.