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Central Metal Atom Inorganic & Coordination Chemistry Dimensionless The metal atom or ion at the heart of a coordination entity, which accepts electron pairs from the ligands. Chalcogens Atomic Structure & Periodicity Dimensionless The group 16 elements — oxygen, sulfur, selenium, tellurium and polonium — collectively known as the ore-forming elements. ns² np⁴ Cloud Chamber Nuclear & Radiochemistry Dimensionless A device that reveals the paths of ionising particles as visible trails of condensed vapour. Core Electron Atomic Structure & Periodicity Dimensionless An electron occupying a completely filled inner shell that does not take part in chemical bonding. Corrosion Electrochemistry & Redox mm/year The gradual destruction of a metal by electrochemical reaction with its environment. Coupled Reactions Thermochemistry & Thermodynamics kJ/mol Two reactions linked through a shared intermediate so that a favourable one drives an unfavourable one. ΔG_total = ΔG₁ + ΔG₂ < 0 Diagonal Relationship Atomic Structure & Periodicity Dimensionless The similarity in properties between an element of period 2 and the element one place to its lower right in period 3. Element Foundations of Chemistry Dimensionless A pure substance composed entirely of atoms that share the same atomic number and therefore cannot be split into simpler substances by chemical means. End Point Acids, Bases & Salts mL The point in a titration at which the indicator changes colour, signalling that the reaction is judged complete. Endothermic Reaction Stoichiometry & Chemical Reactions kJ/mol A reaction that absorbs energy from the surroundings, giving a positive enthalpy change. ΔH > 0 f-Block Elements Atomic Structure & Periodicity Dimensionless The lanthanides and actinides, in which electrons fill the f orbitals of the antepenultimate shell. (n−2)f¹⁻¹⁴ First-Order Reaction Chemical Kinetics & Catalysis s⁻¹ A reaction whose rate is directly proportional to the concentration of a single reactant. ln[A] = ln[A]₀ − kt Free Radical Chain Mechanism Chemical Kinetics & Catalysis Dimensionless A chain mechanism in which the propagating intermediates are species bearing unpaired electrons. X· + RH → HX + R· Frenkel Defect States of Matter & Gas Laws Dimensionless A point defect in which an ion leaves its lattice site and lodges in a nearby interstitial position. Froth Flotation Inorganic & Coordination Chemistry Dimensionless A concentration method that separates minerals by exploiting differences in how readily their surfaces are wetted. Glucose Biochemistry & Polymer Chemistry g/mol The most abundant monosaccharide and the primary energy source for most living cells. C₆H₁₂O₆ Hydration Reaction Stoichiometry & Chemical Reactions Dimensionless The addition of water across a multiple bond or the incorporation of water into a crystal lattice. C=C + H₂O → C(OH)–CH ICE Table Chemical Equilibrium mol/L A systematic tabulation of Initial, Change and Equilibrium amounts used to solve equilibrium problems. Immiscible Liquids Solutions & Colligative Properties Dimensionless Two liquids that do not dissolve in one another and separate into distinct layers. Metalloid Atomic Structure & Periodicity Dimensionless An element with properties intermediate between those of metals and non-metals, lying along the periodic table's staircase. Moderator Nuclear & Radiochemistry Dimensionless A material used in a reactor to slow fast neutrons to energies at which fission is far more probable. Nitrile Organic Chemistry Dimensionless A compound containing a carbon–nitrogen triple bond. R–C≡N Nucleus Atomic Structure & Periodicity m The dense, positively charged core of an atom, containing virtually all of its mass in protons and neutrons. r ≈ 1.2 × A^(1/3) fm Odd-Electron Molecule Chemical Bonding & Molecular Structure Dimensionless A species containing an unpaired electron, so that its total electron count is odd and no octet structure is possible.