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Successive Ionisation Energies Atomic Structure & Periodicity kJ/mol The series of energies required to remove electrons one after another from the same atom. IE₁ < IE₂ < IE₃ … Superacid Acids, Bases & Salts Dimensionless An acid stronger than pure sulfuric acid, capable of protonating species normally regarded as completely non-basic. H₀ < −12 Supercritical Fluid States of Matter & Gas Laws K, Pa A substance held above both its critical temperature and critical pressure, where liquid and gas phases are indistinguishable. T > T_c and p > p_c Supersaturated Solution Solutions & Colligative Properties mol/L An unstable solution containing more dissolved solute than the equilibrium solubility at that temperature. Surface Tension States of Matter & Gas Laws N/m The energy required to increase the surface area of a liquid by unit amount, arising from unbalanced intermolecular forces at the surface. γ = F / L Surroundings Thermochemistry & Thermodynamics Dimensionless Everything outside the chosen system with which it can exchange energy or matter. System Thermochemistry & Thermodynamics Dimensionless The specific part of the universe chosen for thermodynamic study, separated from everything else by a real or imaginary boundary. Systematic Error Analytical Chemistry & Spectroscopy Various An error that shifts every result in the same direction by a similar amount.