Terms starting with H
41 terms · page 2 of 2
Homologous Series
Organic Chemistry
Dimensionless
A family of compounds sharing the same functional group and general formula, with successive members differing by CH₂.
differ by −CH₂−
Hormone
Biochemistry & Polymer Chemistry
mol/L
A chemical messenger released by one tissue that regulates the activity of cells elsewhere in the body.
Hund's Rule of Maximum Multiplicity
Atomic Structure & Periodicity
Dimensionless
The rule that electrons occupy degenerate orbitals singly with parallel spins before any orbital is doubly occupied.
maximise total spin S
Hybridisation
Chemical Bonding & Molecular Structure
Dimensionless
The mixing of atomic orbitals on the same atom to form an equal number of new, equivalent orbitals suited to bonding.
Hydrate
Foundations of Chemistry
Dimensionless
A crystalline compound in which a definite number of water molecules is incorporated into the lattice.
MX·nH₂O
Hydrate Isomerism
Inorganic & Coordination Chemistry
Dimensionless
Isomerism arising from water molecules occupying either the coordination sphere or lattice positions outside it.
Hydration Energy
Solutions & Colligative Properties
kJ/mol
The energy released when one mole of gaseous ions is surrounded by water molecules to form a dilute aqueous solution.
ΔH_hyd ∝ z / r
Hydration Reaction
Stoichiometry & Chemical Reactions
Dimensionless
The addition of water across a multiple bond or the incorporation of water into a crystal lattice.
C=C + H₂O → C(OH)–CH
Hydrocarbon
Organic Chemistry
Dimensionless
A compound composed exclusively of carbon and hydrogen.
CₓH_y
Hydrogen Bond
Chemical Bonding & Molecular Structure
kJ/mol
A strong dipole interaction between a hydrogen atom bonded to N, O or F and a lone pair on another such atom.
X–H···Y (X, Y = N, O, F)
Hydrogen–Oxygen Fuel Cell
Electrochemistry & Redox
V
A fuel cell in which hydrogen is oxidised at the anode and oxygen reduced at the cathode, producing only water.
2H₂ + O₂ → 2H₂O, E° = 1.23 V
Hydrolysis
Stoichiometry & Chemical Reactions
Dimensionless
A reaction in which a bond is cleaved by water, with the H and OH fragments adding to the two products.
AB + H₂O → AOH + BH
Hydrolysis Constant
Acids, Bases & Salts
mol/L
The equilibrium constant for the hydrolysis of a salt ion in water.
Kh = Kw / Ka (anion)
Hyperconjugation
Organic Chemistry
kJ/mol
The stabilising delocalisation of electrons from a sigma C–H bond into an adjacent empty or partly filled p orbital.
Hypertonic Solution
Solutions & Colligative Properties
atm
A solution with a higher osmotic pressure than the one it is compared with, drawing water out of the more dilute side.
π_solution > π_cell
Hypotonic Solution
Solutions & Colligative Properties
atm
A solution with a lower osmotic pressure than the one it is compared with, so water flows into the more concentrated side.
π_solution < π_cell
Hückel's Rule
Organic Chemistry
Dimensionless
The rule that a planar cyclic conjugated system is aromatic if it contains 4n + 2 pi electrons.
4n + 2 π electrons