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Cryoscopic Constant Solutions & Colligative Properties K·kg/mol The freezing point depression produced by a one-molal solution of a non-electrolyte in a given solvent. K_f = RT_f²M / ΔH_fus Crystal Defect States of Matter & Gas Laws Dimensionless Any irregularity that interrupts the perfectly ordered arrangement of particles in a crystal. Crystal Field Splitting Energy Inorganic & Coordination Chemistry cm⁻¹ The energy difference between the sets of d orbitals produced when a ligand field lifts their degeneracy. Δ₀ or Δ_t Crystal Field Stabilisation Energy Inorganic & Coordination Chemistry kJ/mol The net energy gained by a complex through the preferential occupation of lower-energy d orbitals. CFSE = (−0.4n_t2g + 0.6n_eg)Δ₀ Crystal Field Theory Inorganic & Coordination Chemistry kJ/mol The model treating metal–ligand bonding as purely electrostatic and analysing how ligand fields split the metal d orbitals. Crystal Lattice Chemical Bonding & Molecular Structure Dimensionless The regular, repeating three-dimensional arrangement of particles in a crystalline solid. Crystalline Solid States of Matter & Gas Laws Dimensionless A solid in which the constituent particles are arranged in a regular, repeating three-dimensional pattern extending over long distances. Crystallisation Foundations of Chemistry Dimensionless A purification technique in which a solid is separated from solution as an ordered crystalline lattice. Curie Nuclear & Radiochemistry Ci The older unit of radioactivity, defined as the activity of one gram of radium-226. 1 Ci = 3.7 × 10¹⁰ Bq Cyclic Process Thermochemistry & Thermodynamics J A process in which a system undergoes a series of changes and returns to its exact initial state. ΔU = 0, q = −w