Results for “pH”
15 terms
Basic Buffer
Acids, Bases & Salts
Dimensionless
A buffer made from a weak base and one of its salts, giving a pH above 7.
pOH = pKb + log([salt]/[base])
Basic Salt
Acids, Bases & Salts
Dimensionless
A salt whose aqueous solution has a pH above 7, or one that retains a hydroxide group.
Bond Dissociation Enthalpy
Thermochemistry & Thermodynamics
kJ/mol
The enthalpy change when one mole of a specific bond is broken homolytically in the gas phase.
A–B(g) → A·(g) + B·(g)
Buffer Capacity
Acids, Bases & Salts
mol/L
The amount of strong acid or base a buffer can absorb before its pH changes appreciably.
β = dn / d(pH)
Buffer Range
Acids, Bases & Salts
Dimensionless
The span of pH values over which a buffer works effectively, conventionally one unit either side of its pKa.
pH = pKa ± 1
Buffer Solution
Acids, Bases & Salts
Dimensionless
A solution that resists changes in pH when small amounts of acid or base are added.
Basic Solution
Acids, Bases & Salts
mol/L
A solution in which the hydroxide ion concentration exceeds the hydrogen ion concentration.
[OH⁻] > [H⁺]
Boiling Point
States of Matter & Gas Laws
°C
The temperature at which the vapour pressure of a liquid equals the external pressure acting on it.
p_vap = p_external
Boiling Point Elevation
Solutions & Colligative Properties
°C
The rise in a solvent's boiling point caused by the presence of a non-volatile solute.
ΔT_b = i K_b m
Bond Polarity
Chemical Bonding & Molecular Structure
Dimensionless
The degree of unequal electron sharing in a covalent bond, arising from an electronegativity difference between the bonded atoms.
Δχ = |χ_A − χ_B|
Bidentate Ligand
Inorganic & Coordination Chemistry
Dimensionless
A ligand that binds to the same metal centre through two donor atoms, forming a ring.
Bimolecular Reaction
Chemical Kinetics & Catalysis
L/(mol·s)
An elementary step in which two species collide and react.
A + B → products, rate = k[A][B]
Biodegradable Polymer
Biochemistry & Polymer Chemistry
Dimensionless
A polymer that can be broken down into simple substances by the action of microorganisms.
Blank
Analytical Chemistry & Spectroscopy
Various
A sample containing everything except the analyte, measured to correct for background signal.
Body-Centred Cubic
States of Matter & Gas Laws
Dimensionless
A cubic arrangement with particles at the eight corners plus one at the centre of the cell.
2 atoms per cell, 68% packing