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Chemical Bonding & Molecular Structure

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HOMO and LUMO Chemical Bonding & Molecular Structure eV The highest occupied and lowest unoccupied molecular orbitals, which together govern a molecule's reactivity and spectroscopy. ΔE = E_LUMO − E_HOMO Hybridisation Chemical Bonding & Molecular Structure Dimensionless The mixing of atomic orbitals on the same atom to form an equal number of new, equivalent orbitals suited to bonding. Hydrogen Bond Chemical Bonding & Molecular Structure kJ/mol A strong dipole interaction between a hydrogen atom bonded to N, O or F and a lone pair on another such atom. X–H···Y (X, Y = N, O, F)