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Thermodynamics & Statistical Physics

Partition Function

The central mathematical function in statistical mechanics that encodes statistical properties of a system in thermodynamic equilibrium.

Governing formula Z = ∑ exp(-E_i / (kB T)) = ∑ g_i exp(-E_i / (kB T))
SI unit Dimensionless

In depth

Acts as the sum over Boltzmann state weights. All thermodynamic quantities (internal energy, entropy, pressure, free energy) are calculated by taking derivatives of $ln Z$.

Examples in the real world

Deriving Planck's blackbody radiation law or heat capacities of solids using quantum partition functions.