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Condensed Matter & Materials Physics

P-type Semiconductor

An extrinsic semiconductor in which trivalent acceptor impurities create an excess concentration of positive holes as majority charge carriers.

Governing formula p ≈ N_A ≫ n, n p = n_i²
SI unit cm⁻³ (Hole Concentration)

In depth

Doping silicon (valence 4) with trivalent atoms like Boron (valence 3) leaves an unfilled electron bond. Thermal energy easily promotes a valence electron into this acceptor level (E_a), creating a mobile hole in the valence band.

Examples in the real world

Boron-doped silicon forming the p-layer of p-n junction solar cells and LEDs.