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Thermodynamics & Statistical Physics

Isothermal Process

A thermodynamic change in state occurring at a constant temperature throughout the system.

Governing formula ΔT = 0 ⇒ ΔU = 0, Q = W = n R T ln(V2/V1)
SI unit J

In depth

For an ideal gas undergoing isothermal expansion, internal energy remains constant (ΔU = 0), so all heat added Q is fully converted into expansion work W.

Examples in the real world

Slow expansion of gas in a thin-walled metal cylinder immersed in a massive constant-temperature water bath.