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Thermodynamics & Statistical Physics

Equipartition Theorem

A classical statistical mechanics theorem stating that every independent quadratic degree of freedom contributes ½ kB T to a system's average energy in thermal equilibrium.

Governing formula E_avg = (f / 2) kB T
SI unit J

In depth

A monoatomic ideal gas has 3 translational degrees of freedom ($f=3$), yielding $E_{avg} = 1.5 k_B T$. Diatomic molecules at room temp add 2 rotational degrees ($f=5$), yielding $2.5 k_B T$.

Examples in the real world

Predicting molar heat capacity $C_v = 1.5 R$ for noble gases like helium and argon.