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Thermodynamics & Statistical Physics

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Thermal Radiation Thermodynamics & Statistical Physics W The emission of electromagnetic energy from matter due to thermal agitation of its charged constituent particles. P = ε σ A T⁴ (Stefan-Boltzmann Law) Thermal Stress Thermodynamics & Statistical Physics Pa (N/m²) Mechanical stress developed within a material when thermal expansion or contraction is constrained by rigid boundaries. σ = E α ΔT Third Law of Thermodynamics Thermodynamics & Statistical Physics J/K The law stating that as system temperature approaches absolute zero (0 K), entropy of a pure crystalline substance approaches a minimum constant value of zero. lim (T → 0) S = 0 Van der Waals Equation Thermodynamics & Statistical Physics Pa·m³ An equation of state modifying the ideal gas law to account for finite molecular volume and attractive intermolecular forces in real gases. (P + a n² / V²) (V - n b) = n R T Water Equivalent Thermodynamics & Statistical Physics kg (or g) The mass of water that absorbs or releases the exact same amount of heat as a calorimeter body for an identical temperature change. w = m_cal c_cal / c_water Wien's Displacement Law Thermodynamics & Statistical Physics m·K The physical law stating that peak emission wavelength of a blackbody spectrum is inversely proportional to its absolute temperature. λ_max T = b ≈ 2.89777 × 10⁻³ m·K Zeroth Law of Thermodynamics Thermodynamics & Statistical Physics N/A The law stating that if two systems are each in thermal equilibrium with a third system, they are in thermal equilibrium with each other. If T_A = T_C and T_B = T_C, then T_A = T_B